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  XCG Consultants Ltd.
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Remediation of PCE-Impacted Soil and Groundwater underneath a Shopping Centre Using ISCO
Start Date: 11/1/2003
End Date: 5/1/2006
Location: Edmonton, Alberta
Project Scale: Completed, Monitored.
Media Treated: Soil.
Clean up of Site Involved: Site Characterization & Assessment, Treatment, Monitoring.
Site Condition: Soil and groundwater impacted by PCE and its dechlorination byproducts, TCE, DCE, and vinyl chloride at an active commercial mall in Edmonton, Alberta. The geology of the site consists of a clayey fill underlain by a clay till with discontinuous interbedded sand lenses. The water table occurs at a depth of approximately 1.50 to 2.55 metres below ground surface within the clay fill and varying seasonally. The hydraulic conductivity of the fill and till units is less than 10-6 cm/sec with the horizontal hydraulic gradient being less than 0.01. the groundwater velocity is estimated to be less than 1 cm per year. Due to the presence of the mall over the impacted media, infiltration of precipitation is limited.
Proposed Site Usage: Continued use as an active Commercial Mall
Reasons for Success: The application of the ISCO system allowed the owner of the mall to complete the transaction while providing a 60% cost savings over another recommended remedial approach.
Regulatory Approvals Required: n/a
Exceedance of Set Standards: n/a
Technologies Used:
ISCO - The oxidant, potassium permanganate, was delivered passively to the impacted media via a series of horizontal weeping tiles and vertical injection wells that were installed below the existing floor.
Description:
Halogenated ethenes such as tetrachloroethylene (PCE) and trichloroethylene (TCE) are among the most common groundwater contaminants (Squillace, 2002). A variety of remedial approaches have been developed to address impacts from halogenated ethenes ranging from monitored natural attenuation to excavation and disposal at off-site facilities. One approach to addressing groundwater and soil impacts from PCE and TCE is in-situ chemical oxidation (ISCO). This approach involves treating the soil and groundwater, usually in-situ, with a chemical oxidant. Various oxidants are available including ozone, hydrogen peroxide, hypochlorites, Fentons Reagent, and potassium and sodium permanganate.

The results of the injection program, which was carried out over a six-month period, reduced the soil and groundwater concentrations of PCE by greater than 98%.




Emissions/Byproducts: n/a
Source of Information: XCG Consultants